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White Phosphorus Munition

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01In brief

White phosphorus munition is a type of munition containing white phosphorus for military purposes including smoke screening, signalling, target marking, and incendiary effects. The substance ignites on exposure to air, producing dense white smoke, and its combustion can generate temperatures above 800°C. Its military applications coexist with serious hazards: burning particles can cause deep burns, ignite surrounding material, and reignite after drying. The distinction between incendiary effects and effects produced through toxicity is important to its classification under chemical-weapons definitions.

02Overview

Smoke production and intense combustion are the principal properties exploited in white-phosphorus munitions: the same substance can provide battlefield obscuration or serve an incendiary purpose.[1] Smoke screens limit an opponent’s field of vision and can disrupt optical tracking and targeting.[3] Military applications also include signalling, marking targets, and illumination.[2]

White phosphorus is a highly reactive and toxic form of phosphorus that can ignite in air at approximately 35°C (95°F).[5] Its reactivity requires storage under water or another inert liquid.[5] Contact with burning material can cause severe skin burns, while its heat can ignite vegetation and other flammable objects.[3]

A munition’s chemical contents alone do not determine whether it is a chemical weapon: white-phosphorus weapons whose primary effect depends on incendiary properties rather than toxicity are not chemical weapons under the definition used by the Chemical Weapons Convention.[4] This distinction concerns the mechanism of the weapon’s effects, rather than an absence of injury hazards.[1][4]

03Origins and History

White phosphorus has been used militarily since World War I, both as an incendiary agent and to generate smoke screens or signals.[1] Its use has extended across aircraft bombs, artillery and mortar projectiles, air-to-ground rocket warheads, landmines, and hand- and rifle-grenades.[1] Projectiles containing the substance have served both incendiary and smoke-screening or smoke-marking purposes.[1]

During Operation Cast Lead, fought from 27 December 2008 to 18 January 2009, Israel used white-phosphorus munitions in forms that included exploding munitions and smoke-screening projectiles.[6][7] The Israeli government’s account distinguished a small number of exploding shells used by ground and naval forces for marking and signalling in open, unpopulated areas from the smoke shells that constituted the main white-phosphorus munitions used during the operation.[7] That account also described one use in an open area to uncover tunnel entrances.[7]

A precautionary decision to stop using the exploding munitions was made on 7 January 2009, although a subsequent Israeli investigation identified two further marking uses after that date.[7] The decision did not amount to a simultaneous end to the acknowledged use of white-phosphorus smoke projectiles.[6]

In April 2013, the Israeli army announced that it would replace white-phosphorus shells with shells based entirely on gas, without specifying a retirement date.[8] In 2023, the IDF stated that its principal smoke shells did not contain white phosphorus, while acknowledging that it still possessed some white-phosphorus smoke shells.[9] It described operational considerations and availability as factors affecting the choice of smoke munition.[9]

04Practice and Application

Battlefield obscuration uses the dense white smoke generated when phosphorus burns in air to reduce visibility.[1] By limiting observation, a screen can interfere with an opponent’s optical tracking and targeting.[3] During the 2008–09 Gaza operation, the stated purpose of Israel’s white-phosphorus smoke shells was to screen ground forces from observation and anti-tank units.[7] The Israeli operational account described air-burst deployment using delay fuses at least 100 metres above the ground.[7]

One documented smoke-projectile design was a 155-mm howitzer-fired canister shell timed to burst in the air and disperse approximately 160 white-phosphorus-impregnated felt wedges in a fan-shaped pattern.[10] The wedges ignited on contact with air and emitted smoke until their phosphorus was exhausted or deprived of air.[10] This design distributed smoke-producing material rather than relying on a single point of combustion.[10]

Incendiary applications exploit the substance’s ability to start fires in vegetation or other combustible material.[3] Burning vegetation in open areas can expose concealed military compounds, tunnel shafts, bunkers, or weapons.[3] Other military applications use the visible smoke for marking and signalling rather than destruction.[1] White phosphorus has also been used for illumination.[2]

The distinction between these purposes is reflected in the range of delivery systems: aircraft bombs, artillery and mortar rounds, rocket warheads, mines, and grenades have all contained white-phosphorus formulations.[1] A projectile containing the substance may therefore be used for smoke screening or smoke marking as well as for an incendiary purpose.[1] Israel’s account of its Gaza smoke shells acknowledged incidental incendiary effects while maintaining that their purpose was screening, not attacking personnel or destroying buildings.[7]

Burning particles can remain hazardous after initial deployment because they may be difficult to extinguish and can reignite when dry.[1] In Gaza, dispersed felt wedges remained active for periods reported as long as 21–24 days after discharge, and children were subsequently injured after contact with them.[10] Smoke emission continued while phosphorus remained available and exposed to air.[10]

05Significance

Deep burns are a major consequence of burning phosphorus contacting skin.[1] Particles that remain alight can damage muscles and deeper tissues, potentially causing permanent loss of motor function.[1] Embedded phosphorus can also produce systemic toxic effects, including potentially lethal injury to the liver, heart, kidneys, and blood-generating organs.[1]

Medical accounts from the 2008–09 Gaza conflict described deep tissue and organ damage that was not always apparent initially, with some wounds worsening after patients left hospital.[11] Doctors also described fragments that continued to smoke when bandages were removed.[11] The reported treatment involved keeping the material wet and removing embedded particles and affected tissue.[11]

Weapon classification distinguishes thermal destruction from poisoning: incendiary weapons such as napalm and phosphorus are not classified as chemical-warfare agents when their destructive power is primarily thermal.[12] Smoke-producing obscurant rounds likewise are not viewed as chemical weapons merely because chemicals generate their smoke.[12] For white-phosphorus weapons specifically, the relevant distinction is whether their primary effect depends on incendiary properties rather than toxicity.[4]

International humanitarian law requires assessment of attacks under distinction, proportionality, and precautions, including feasible steps to verify targets and minimize incidental civilian casualties and damage.[13] Those obligations apply to choices of weapons and methods of attack, not only to whether a weapon type is expressly prohibited.[13] Legal assessment of white-phosphorus use consequently involves its manner of employment as well as the classification of the munition.[13][14]

06Controversies

Protocol III of the Convention on Certain Conventional Weapons restricts attacks with incendiary weapons, including attacks involving civilians and military objectives within concentrations of civilians.[14] The United States executive branch has interpreted white phosphorus as outside the protocol’s incendiary-weapon definition; Israel’s position similarly excludes smoke projectiles with incidental incendiary effects, while recognizing that other laws of armed conflict still apply.[14][7] Israel is not a party to Protocol III.[2]

The 2009 Gaza fact-finding inquiry criticized white-phosphorus use in built-up areas and recommended consideration of further controls, while acknowledging that the substance was not generally prohibited under international law.[11] At the UNRWA compound on 15 January 2009, at least seven container shells struck or discharged substantially within a site sheltering 600–700 civilians and containing substantial fuel stores; the inquiry concluded that feasible precautions had not all been taken.[11] Israel maintained that the shells screened forces from anti-tank crews, reported three injuries and property damage, and said smoke-projectile use in that area stopped after the incident.[7] The inquiry also criticized use around al-Quds and al-Wafa hospitals.[11]

In October 2023, Human Rights Watch alleged white-phosphorus use in Gaza and Lebanon; the reporting carried an independent-verification caveat, and the IDF denied the Gaza accusation.[2] In June 2024, further allegations concerned residential buildings in five southern Lebanese communities; the underlying investigation reported no evidence of burn injuries but accounts suggesting possible respiratory damage.[15] Israel maintained that its use was for screening rather than targeting civilians.[15] The IDF also stated that procedures barred use in built-up areas except in exceptional circumstances, reflecting a 2013 undertaking whose two exceptions were disclosed only to the Supreme Court.[9]

Sources

  1. 1Library of Congress, Weapons That May Cause Unnecessary Suffering or Have Indiscriminate Effects, accessed on November 12, 2026.
  2. 2The Jerusalem Post, Human Rights Watch says Israel used white phosphorus in Gaza, Lebanon, accessed on November 12, 2026.
  3. 3Institute for National Security Studies, The Use of White Phosphorus Bombs: What is the Issue?, accessed on November 12, 2026.
  4. 4Encyclopedia.com, Chemical Weapons, accessed on November 12, 2026.
  5. 5Encyclopaedia Britannica, Phosphorus: Properties and Reactions, accessed on November 12, 2026.
  6. 6United Nations Digital Library, UN Fact-Finding Mission on the Gaza Conflict, A/HRC/12/48, accessed on November 12, 2026.
  7. 7Israeli Government, The Operation in Gaza: Factual and Legal Aspects, accessed on November 12, 2026.
  8. 8The Times of Israel, IDF to Halt Use of White Phosphorus, accessed on November 12, 2026.
  9. 9Ynet, The White House is concerned by reports of Israeli use of phosphorus bombs. IDF: We do not attack with them, accessed on November 12, 2026.
  10. 10UN Fact-Finding Mission, A/HRC/12/48, Government-Hosted Copy, accessed on November 12, 2026.
  11. 11Jewish Virtual Library, UN Fact-Finding Mission, accessed on November 12, 2026.
  12. 12The Washington Institute for Near East Policy, Implications of Possible Chemical Weapons Use in Syria, accessed on November 12, 2026.
  13. 13Institute for National Security Studies, Knut Doermann, Obligations of International Humanitarian Law, accessed on November 12, 2026.
  14. 14Congress.gov, U.S. Senate Committee on Foreign Relations, Executive Report 110-22, accessed on November 12, 2026.
  15. 15The Times of Israel, White Phosphorus Allegations in Lebanon, accessed on November 12, 2026.

IsraelPedia Question & Answers

  • What is a white phosphorus munition?

    A white phosphorus munition is a military weapon containing white phosphorus, used for smoke screening, signalling, marking targets, illumination, or incendiary effects. When exposed to air, the substance ignites and produces dense white smoke, while its combustion can generate temperatures above 800°C. Its uses carry serious hazards because burning particles can cause deep burns, ignite nearby material, and reignite after drying.

  • When did military forces begin using white phosphorus?

    White phosphorus has been used militarily since World War I, both as an incendiary agent and to produce smoke screens or signals. Munitions containing it have included aircraft bombs, artillery and mortar projectiles, rocket warheads, landmines, and hand- and rifle-grenades.

  • How did Israel use white-phosphorus munitions during Operation Cast Lead?

    During Operation Cast Lead, fought from 27 December 2008 to 18 January 2009, Israel used exploding munitions and smoke-screening projectiles. Israel’s account said the smoke shells were mainly used to screen ground forces from observation and anti-tank units, while a small number of exploding shells were used for marking and signalling in open, unpopulated areas. It also described one use in an open area to uncover tunnel entrances.

  • How do white-phosphorus smoke shells work?

    White-phosphorus smoke shells disperse burning phosphorus, which produces dense white smoke when exposed to air. One documented design was a 155-mm howitzer-fired canister shell that dispersed approximately 160 phosphorus-impregnated felt wedges in a fan-shaped pattern. The wedges ignited on contact with air and emitted smoke until their phosphorus was exhausted or deprived of air.

  • What injuries can white phosphorus cause?

    Burning white-phosphorus particles can cause deep skin burns and damage muscles and deeper tissues, potentially causing permanent loss of motor function. Embedded phosphorus can also produce systemic toxic effects, including potentially lethal injury to the liver, heart, kidneys, and blood-generating organs. Particles may be difficult to extinguish and can reignite when dry.

  • Are white-phosphorus munitions chemical weapons?

    White-phosphorus munitions are not classified as chemical weapons under the Chemical Weapons Convention definition when their primary effect depends on incendiary properties rather than toxicity. The classification concerns how the weapon produces its effects, not whether it can cause serious injury. Legal assessment of its use also considers the manner of employment and the applicable requirements to distinguish targets, assess proportionality, and take precautions.

  • What has Israel said about replacing or using white-phosphorus smoke shells?

    In April 2013, the Israeli army announced that it would replace white-phosphorus shells with shells based entirely on gas, without specifying a retirement date. In 2023, the IDF said its principal smoke shells did not contain white phosphorus, while acknowledging that it still possessed some white-phosphorus smoke shells. It cited operational considerations and availability as factors in choosing a smoke munition.